胡萝卜丁中维生素C在热风辅助射频干燥过程中降解的动力学模型

目的研究热风辅助射频(hot air-assisted radio frequency,HA-RF)干燥过程中维生素C随温度变化的降解动力学模型。方法在6.5 cm极板间距和60℃热风系统条件下进行HA-RF干燥,重点研究胡萝卜丁中维生素C在干燥过程中的降解动力学,包括脱氢抗坏血酸(dehydroascorbic acid,DHAA)和抗坏血酸(ascorbic acid,AA)。总维生素C含量采用2,4-硝基苯肼分光光度法测定,AA采用2,6-二氯吲哚酚滴定法测定。结果HA-RF干燥过程中维生素C的降解规律符合一级可逆模型,其降解活化能为40.54 kJ/mol。DHAA活化能为35.83 kJ/mol,表明DHAA的稳定性低于AA。结论本研究使用的干燥温度为62.5~77.5℃,较高的干燥温度下维生素C降解速率较高,较低处理温度下的降解过程具有更好的模型适应度(R2>0.98)。     

三网融合下广电媒体网内整合模式创新探讨

广电行业2010年进入改革阶段,目前进入深化改革阶段,此番改革是前所未有的,是三网融合背景下行业发展的必然趋势。立足广电媒体工作实践,从三网融合背景出发,探究广电媒体网内整合的创新模式,以期能够促进广电媒体发展,加快网内整合步伐。     

光学材料的磨削损伤控制试验研究

基于K9玻璃不同的磨削工艺参数确定其磨削损伤层深度随工艺参数变化的规律，并通过工件磨削损伤层深度的动态检测研究其裂纹扩展规律。结果表明:工件磨削过程中的裂纹损伤是动态扩展过程。固定工艺参数下，裂纹稳态扩展，损伤层深度不变；采用损伤更小的工艺参数磨削，裂纹的扩展速度小于材料的去除速度，其损伤层深度逐渐减小，损伤的去除速度逐渐减慢直至二者间达到稳态平衡。同时，为了去除前道工序的损伤层，后道工序的材料去除量需达到前道工序损伤层深度的2～3倍。      

Study on flame propagation of premixed N2O–NH3/N2O–NH3–C3H8 in cylindrical vessels

The flame propagation behavior of premixed N₂O–NH₃/N₂O–NH₃–C₃H₈ was experimentally investigated in elongated vented cylindrical vessels with central ignition. The effect of vessel diameter and propane concentration ([C₃H₈] = 1.96–7.41 wt.%) on the process of flame acceleration was studied and discussed. The results revealed that the maximum value of flame acceleration rate was found in the cylindrical vessel with an inner diameter of 7 mm, followed by 5 mm, 10 mm, and 15 mm. At a constant vessel diameter, the rate of flame acceleration was noticeably improved by adding propane ([C₃H₈] = 1.96–3.85 wt.%) to the premixed N₂O–NH₃. However, a further increase in the propane fraction up to 5.66%, caused a decline in the flame acceleration rate, probably as a consequence of a combined effect between the reduction of oxygen and greater dilution of the ammonia in the total concentration.     

基于双层修正无迹卡尔曼的水下节点定位算法* .txt

摘要：针对水下无线传感网络中运动节点定位精度低的问题，提出了一种新的基于双层修正无迹卡尔曼的水下节点定位算法(DLMUKF)。该算法利用下层无迹卡尔曼滤波算法对节点状态进行预测，根据各信标节点的测距传播时延对预测的节点状态进行修正。运用上层无迹卡尔曼滤波算法对修正后的状态进行新的预测与修正。仿真实验中，DLMUKF算法的平均定位误差约为传统多边定位算法的15%，约为基于无迹卡尔曼滤波（UKF）定位算法的16%，受节点运动时间与速度的影响最小。通过实验证明DLMUKF算法能更充分利用实际距离值，可以有效减小运动节点的定位误差。 .txt     

Ferroelastic domain switching and R-curve behavior in lead zirconate titanate (Zr/Ti = 52/48)-based ferroelectric ceramics

In this work, ferroelastic domain switching and R-curve behavior in lead zirconate titanate (Nb/Ce co-doped Pb(Zr_0.52Ti_0.48)O₃, ab. PZT-NC)-based ferroelectric ceramics were investigated, using the indentation-strength-in-bending (ISB) method. Firstly, Vickers indentation test examined the notable fracture anisotropy of PZT-NC ceramics between the poling direction and its perpendicular direction, and the crack open displacement (COD) profiles in the two directions were also theoretically calculated from the indentation fracture mechanics. And then two kinds of ferroelastic domain switching modes (in-plane and out-of-plane) were used for explaining such anisotropic propagation behavior of indentation cracks. The subsequent three-point bending test illustrated the dependence of fracture strength on indentation load and the rising crack growth resistance curves (R-curves) in two directions. The resulted R-curves were fitted by the Hill's type Growth Function successfully, giving the reasonable values of crack extension exponential (n), plateau fracture toughness (K_max), and initial fracture toughness (K_ini). The in-plane ferroelastic domain switching was identified as a more significant toughening mechanism for PZT-NC ceramics than the out-of-plane switching due to more switchable domains.     

Reconstruction of the Grenfell Tower fire – Part 4: Contribution to the understanding of fire propagation and behaviour during horizontal fire spread

The tragic events at Grenfell Tower in 2017, involving a combustible façade system, have raised concerns regarding the fire risk that these systems pose. In this series of articles, so far published, fire development inside the initial apartment has been investigated using an appropriate computational fluid dynamics (CFD) model. Several scenarios including different fire sources and ventilation conditions were addressed. Fire propagation through the window to the external façade and to higher apartments was modelled. This model was validated by comparing the numerical results with the visual observations reported in the Grenfell Inquiry. A CFD model of the complete east face of the Grenfell Tower was then created. This paper details CFD modelling of the complete Grenfell Tower façade during the late horizontal phase of fire spread. As the physics of lateral flame spread is different from that for upward flame spread, it is important to assess the validity of the model, thus far developed, for this configuration. Fire propagation over the whole façade is modelled and compared with observations from the real disaster. This provides a better understanding of its fire behaviour and of the contribution of architectural details and their impact on fire spread.     

Rock brittleness indices and their applications to different fields of rock engineering:A review

Brittleness is an important parameter controlling the mechanical behavior and failure characteristics of rocks under loading and unloading conditions,such as fracability,cutability,drillability and rockburst proneness.As such,it is of high practical value to correctly evaluate rock brittleness.However,the definition and measurement method of rock brittleness have been very diverse and not yet been standardized.In this paper,the definitions of rock brittleness are firstly reviewed,and several representative definitions of rock brittleness are identified and briefly discussed.The development and role of rock brittleness in different fields of rock engineering are also studied.Eighty brittleness indices publicly available in rock mechanics literature are compiled,and the measurement method,applicability and limitations of some indices are discussed.The results show that(1)the large number of brittleness indices and brittleness definitions is attributed to the different foci on the rock behavior when it breaks;(2)indices developed in one field usually are not directly applicable to other fields;and(3)the term“brittleness”is sometimes misused,and many empirically-obtained brittleness indices,which lack theoretical basis,fail to truly reflect rock brittleness.On the basis of this review,three measurement methods are identified,i.e.(1)elastic deformation before fracture,(2)shape of post-peak stressestrain curves,and(3)methods based on fracture mechanics theory,which have the potential to be further refined and unified to become the standard measurement methods of rock brittleness.It is highly beneficial for the rock mechanics community to develop a robust definition of rock brittleness.This study will undoubtedly provide a comprehensive timely reference for selecting an appropriate brittleness index for their applications,and will also pave the way for the development of a standard definition and measurement method of rock brittleness in the long term.     

Impact of the occurrence probability of carbon black agglomerates on the measured and predicted durability of filled elastomers

This work analyses the impact of the sample geometry on the stress or strain concentration and the occurrence of big agglomerates in the investigated test volume. Although the three investigated dumbbell test specimens were loaded at the same stress level, there were significant differences in measured lifetime. These differences in the lifetime are due to the occurrence of the large agglomerates in the tested volume. The probability of occurrence of large agglomerates increases with increase in the investigated volume. In the lifetime prediction by Monte Carlo method, this effect is realized by changing the quantity of the distributed agglomerates in the mesh of the simulated model. The prediction of the different sample geometries shows a very good agreement with the measurement points. The numerical simulations illustrate the stress increase for the three used lifetime test samples.